Europium

Europium is a chemical element wi the seembol Eu an atomic nummer 63. It is named efter the continent Europe. It is a moderately haird, sillery metal whilk readily oxidizes in air an watter. Bein a teepical member o the lanthanide series, europium uisually assumes the oxidation state +3, but the oxidation state +2 is common an aa: aw europium compoonds wi oxidation state +2 are slichtly reducing. Europium haes na signeeficant biological role an is relatively non-toxic compared tae ither hivy metals. Maist applications o europium exploit the phosphorescence o europium compoonds.

Europium, 63Eu
Template:Infobox element/symbol-to-top-image/alt
Europium
Pronunciation/j[unsupported input]piəm/ (yoor-OH-pee-əm)
Appearancesillrry white, wi a pale yellsr tint;[1] but rarely seen without oxide discoloration
Standard atomic weight Ar, std(Eu)151.964(1)[2]
Europium in the periodic cairt
HydrogenHelium
LithiumBerylliumBoronCarbonNitrogenOxygenFluorineNeon
SodiumMagnesiumAluminiumSiliconPhosphorusSulfurChlorineArgon
PotassiumCalciumScandiumTitaniumVanadiumChromiumManganeseAirnCobaltNickelCapperZincGalliumGermaniumArsenicSeleniumBromineKrypton
RubidiumStrontiumYttriumZirconiumNiobiumMolybdenumTechnetiumRutheniumRhodiumPalladiumSiller (element)CadmiumIndiumTinAntimonyTelluriumIodineXenon
CaesiumBariumLanthanumCeriumPraseodymiumNeodymiumPromethiumSamariumEuropiumGadoliniumTerbiumDysprosiumHolmiumErbiumThuliumYtterbiumLutetiumHafniumTantalumTungstenRheniumOsmiumIridiumPlatinumGowdMercur (element)ThalliumLeid (element)BismuthPoloniumAstatineRadon
FranciumRadiumActiniumThoriumProtactiniumUraniumNeptuniumPlutoniumAmericiumCuriumBerkeliumCaliforniumEinsteiniumFermiumMendeleviumNobeliumLawrenciumRutherfordiumDubniumSeaborgiumBohriumHassiumMeitneriumDarmstadtiumRoentgeniumCoperniciumUnuntriumFleroviumUnunpentiumLivermoriumUnunseptiumUnunoctium


Eu

Am
samariumeuropiumgadolinium
Atomic nummer (Z)63
Groupgroup n/a
Periodperiod 6
Blockf-block
Element category  Lanthanide
Electron confeeguration[Xe] 4f7 6s2
Electrons per shell2, 8, 18, 25, 8, 2
Pheesical properties
Phase at STPsolid
Meltin pynt1099 K ​(826 °C, ​1519 °F)
Bylin pynt1802 K ​(1529 °C, ​2784 °F)
Density (near r.t.)5.264 g/cm3
when liquid (at m.p.)5.13 g/cm3
Heat o fusion9.21 kJ/mol
Heat o vapourisation176 kJ/mol
Molar heat capacity27.66 J/(mol·K)
Vapour pressur
P (Pa)1101001 k10 k100 k
at T (K)8639571072123414521796
Atomic properties
Oxidation states+1, +2, +3 (a mildly basic oxide)
ElectronegativityPauling scale: 1.2
Ionisation energies
  • 1st: 547.1 kJ/mol
  • 2nd: 1085 kJ/mol
  • 3rd: 2404 kJ/mol
Atomic radiusempirical: 180 pm
Covalent radius198±6 pm
Colour lines in a spectral range
Colour lines in a spectral range
Spectral lines o europium
Ither properties
Naitural occurrenceprimordial
Creestal structur ​bouk-centred cubic
[[File:bouk-centred cubic|frameless|alt=Bouk-centred cubic creestal structur for europium|upright=0.23|Bouk-centred cubic creestal structur for europium]]
Thermal expansionpoly: 35.0 µm/(m·K) (at r.t.)
Thermal conductivityest. 13.9 W/(m·K)
Electrical resistivitypoly: 0.900 µΩ·m (at r.t.)
Magnetic orderinparamagnetic[3]
Magnetic susceptibility+34,000.0·10−6 cm3/mol[4]
Young's modulus18.2 GPa
Shear modulus7.9 GPa
Bulk modulus8.3 GPa
Poisson ratio0.152
Vickers haurdness165–200 MPa
CAS Nummer7440-53-1
History
Naminefter Europe
Diskivery an first isolationEugène-Anatole Demarçay (1896, 1901)
Main isotopes o europium
Iso­topeAbun­danceHauf-life (t1/2)Decay modePro­duct
150Eusyn36.9 yε150Sm
151Eu47.8%5×1018 yα147Pm
152Eusyn13.54 yε152Sm
β152Gd
153Eu52.2%stable
154Eusyn8.59 yβ154Gd
155Eusyn4.76 yβ155Gd
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References eedit

  1. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth–Heinemann. p. 112. ISBN 0080379419.
  2. Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
  3. Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  4. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.