Hexanitrostilbene (HNS), also called JD-X, is an organic compound with the formula [(O2N)3C6H2CH]2. It is a yellow-orange solid.[1] It is used as a heat-resistant high explosive. It is slightly soluble (0.1 - 5 g/100 mL) in butyrolactone, DMF, DMSO, and N-methylpyrrolidone.
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| Names | |
|---|---|
| Preferred IUPAC name 1,1′-[(E)-Ethane-1,2-diyl]bis(2,4,6-trinitrobenzene) | |
| Other names 1,2-bis-(2,4,6-trinitrophenyl)-ethylene; hexanitrodiphenylethylene, HNS | |
| Identifiers | |
3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.039.525 |
PubChem CID | |
| UN number | 0392 TNT mixtures: 0388, 0389 |
CompTox Dashboard (EPA) | |
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| Properties | |
| C14H6N6O12 | |
| Molar mass | 450.23 g/mol |
| Appearance | Yellow crystalline powder |
| Density | 1.7 g/cm3 |
| Melting point | 316 °C (601 °F; 589 K) |
| Explosive data | |
| Shock sensitivity | Low |
| Friction sensitivity | Low |
| Detonation velocity | 7000 m/s |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Production and use
editIt is produced by oxidizing trinitrotoluene (TNT) with a solution of sodium hypochlorite. HNS boasts a higher insensitivity to heat than TNT, and like TNT it is insensitive to impact. When casting TNT, HNS is added at 0.5% to form erratic micro-crystals within the TNT, which prevent cracking.[1] Because of its insensitivity but high explosive properties, HNS is used in space missions. It was the main explosive fill in the seismic source generating mortar ammunition canisters used as part of the Apollo Lunar Active Seismic Experiments.[2]
Its heat of detonation is 4 kJ/g.[3]
It was developed by Kathryn Grove Shipp at the U.S. Naval Ordnance Laboratory in the 1960s and has been improved on since then.[4]
See also
editReferences
edit- ^ a b Jacques Boileau, Claude Fauquignon, Bernard Hueber and Hans H. Meyer "Explosives" in Ullmann's Encyclopedia of Industrial Chemistry, 2009, Wiley-VCH, Weinheim. doi:10.1002/14356007.a10_143.pub2
- ^ NASA reference publication
- ^ Hexanitrostilbene and Its Properties[permanent dead link]
- ^ Peter Golding, Asoka M. Jayaweera-Bandara, Henry Duffin, "Production of HNS" Patent 5023386. Filed: January 4, 1990.