No. Portrait Governor From Until Monarch 1 Antonio de Mendoza 14 November 1535 25 November 1550 Charles I 2 Luís de Velasco 25 November 1550 31 July 1564 3 Gastón Carrillo de Peralta y Bosquete , 3rd Marquess of Falces19 October 1566 11 November 1567 Philip II 4 Martín Enríquez de Almanza 5 November 1568 4 October 1580 5 Lorenzo Suárez de Mendoza , 4th Count of La Coruña4 October 1580 19 June 1583 6 Pedro de Moya y Contrerás (Archbishop of Mexico )25 September 1584 17 October 1585 7 Álvaro Manrique de Zúñiga 1st Marquess of Villamanrique17 October 1585 27 January 1590 8 Luís de Velasco Marquess of Salinas27 January 1590 5 November 1595 9 Gaspar de Zúñiga Acevedo y Fonseca , 5th Count of Monterrey5 November 1595 27 October 1603 10 Juan de Mendoza y Luna , Marquess of Montesclaros27 October 1603 2 July 1607 Philip III 11 Luís de Velasco , Marquess of Salinas2 July 1607 19 June 1611 12 García Guerra , O.P. (Archbishop of Mexico )19 June 1611 22 February 1612 Int. Pedro Otárola , Dean of the Audiencia 22 February 1612 18 October 1612 13 Diego Fernández de Córdoba , Marquess of Guadalcázar and Count of Posadas18 October 1612 14 March 1621 Int. Paz de Valecillo , Dean of the Audiencia 14 March 1621 11 September 1621 14 Diego Carrillo de Mendoza y Pimentel , 1st Marquess of Gélves21 September 1621 1 November 1624 Philip IV Vacant Due to the discrepancy on the arrival of successor Viceroy from 1 to 3 November 1624. 15 Rodrigo Pacheco y Osorio de Toledo , 3rd Marquess of Cerralvo3 November 1624 16 September 1635 16 Lope Díez de Aux de Armendáriz , Marquess of Cadreita16 September 1635 28 August 1640 17 Diego Roque López Pacheco Cabrera y Bobadilla , 7th Duke of Escalona, 7th Marquess of Villena and 7th Count of Xiquena28 August 1640 10 June 1642 18 Juan de Palafox y Mendoza (Bishop of Puebla )10 June 1642 23 November 1642 19 García Sarmiento de Sotomayor , 2nd Count of Salvatierra and Marquess of Sobroso23 November 1642 14 May 1648 20 Marcos de Torres y Rueda (Bishop of Yucatan )15 May 1648 22 April 1649 Int. Matías de Peralta , Dean of the Audiencia 22 April 1649 28 June 1650 21 Luis Enríquez de Guzmán , 9th Count of Alba de Liste and Marquess of Villaflor28 June 1650 15 August 1653 22 Francisco Fernández de la Cueva, 8th Duke of Alburquerque, Marquess of Cuéllar, Count of Ledesma and of Huelma15 August 1653 16 September 1660 23 Juan de Leyva de la Cerda , Marquess of Adrada16 September 1660 29 June 1664 24 Diego Osorio de Escobar y Llamas (Bishop of Puebla )29 June 1664 15 October 1664 25 Antonio Sebastián de Toledo Molina y Salazar , 2nd Marquess of Mancera16 October 1664 20 November 1673 26 Pedro Nuño Colón de Portugal y Castro , 6th Duke of Veragua, 6th Marquess of Jamaica and 6th Count of Gelves20 November 1673 13 December 1673 Charles II 27 Payo Enríquez de Rivera Manrique , O.S.A. (Bishop of Guatemala and Archbishop of Mexico )13 December 1673 7 November 1680 28 Tomás Antonio Manuel Lorenzo de la Cerda y Aragón 3rd Marquess of La Laguna de Camero Viejo7 November 1680 16 June 1686 29 Melchor Portocarrero y Lasso de la Vega , 3rd Count of Monclova16 June 1686 20 November 1688 30 Gaspar Melchor Baltasar de la Cerda Silva Sandoval y Mendoza , 8th Count of Galve, Lord of Salcedón and Tortola20 November 1688 27 February 1696 31 Juan de Ortega Cano Montañez y Patiño (Bishop of Durango , Guatemala , Michoacán and Archbishop of Mexico )27 February 1696 18 December 1696 32 José Sarmiento Valladares Arines de Romay , 1st Duke of Atrisco, Count of Moctezuma and of Tula18 December 1696 4 November 1701 33 Juan de Ortega Cano Montañez y Patiño (Archbishop of Mexico )4 November 1701 27 November 1702 Philip V 34 Francisco V Fernández de la Cueva Enríquez y Fernández de la Cueva , 10th Duke of Alburquerque and Marquess of Cuéllar27 November 1702 13 November 1710 35 Fernando de Alencastre Noroña y Silva , 1st Duke of Linares and Marquess of Valdefuentes13 November 1710 16 July 1716 36 Baltasar de Zúñiga Guzmán Sotomayor y Mendoza , 1st Duke of Arión and Marquess of Valero16 July 1716 15 October 1722 37 Juan de Acuña y Bejarano , 2nd Marquess of Casa Fuerte15 October 1722 17 March 1734 Louis I From 1700 to 1724, Philip V was the king; then from 1724 to 1746. Louis I only reigned in 1724. 38 Juan Antonio de Vizarrón y Eguiarreta (Archbishop of Mexico )17 March 1734 17 August 1740 Philip V 39 Pedro de Castro Figueroa y Salazar , 1st Duke of La Conquista and 1st Marquess of Gracia Real17 August 1740 22 August 1741 Int. Pedro Malo de Villavicencio , President of the Audiencia 23 August 1741 2 November 1742 40 Pedro Cebrián y Agustín , 5th Count of Fuenclara3 November 1742 9 July 1746 41 Juan Francisco de Güemes y Horcasitas , 1st Count of Revillagigedo9 July 1746 9 November 1755 Ferdinand VI 42 Agustín de Ahumada y Villalón , Marquess of Amarillas10 November 1755 5 February 1760 Int. Francisco Antonio de Echávarri , Dean of the Audiencia 5 February 1760 28 April 1760 43 Francisco Cajigal de la Vega 28 April 1760 5 October 1760 Charles III 44 Joaquín de Montserrat , Marquess of Cruillas5 October 1760 24 August 1766 45 Carlos Francisco de Croix, Marquess of Croix24 August 1766 22 September 1771 46 Antonio María de Bucareli y Ursúa 22 September 1771 9 April 1779 Int. Francisco Romá y Rosell , Regent of the Audiencia 10 April 1779 22 August 1779 47 Martín de Mayorga Ferrer ,Captain General of Guatemala 23 August 1779 28 April 1783 48 Matías de Gálvez y Gallardo ,Captain General of Guatemala 28 April 1783 20 October 1784 Int. Vicente de Herrera y Rivero , Regent of the Audiencia 20 October 1784 17 June 1785 49 Bernardo de Gálvez y Madrid , 1st Viscount of Galveston and 1st Count of Gálvez17 June 1785 30 November 1786 Int. Eusebio Sánchez Pareja y Beleño Regent of the Audiencia 30 November 1786 8 May 1787 50 Alonso Núñez de Haro y Peralta (Archbishop of Mexico )8 May 1787 16 August 1787 51 Manuel Antonio Flórez Maldonado 16 August 1787 16 October 1789 52 Juan Vicente de Güemes Pacheco de Padilla y Horcasitas , 2nd Count of Revillagigedo17 October 1789 11 July 1794 Charles IV 53 Miguel de la Grúa Talamanca de Carini y Branciforte , 1st Marquess of Branciforte12 July 1794 31 May 1798 54 Miguel José de Azanza Alegría , 1st Duke of Santa Fe31 May 1798 30 April 1800 55 Félix Berenguer de Marquina 30 April 1800 4 January 1803 56 José de Iturrigaray 4 January 1803 16 September 1808 57 Pedro de Garibay 16 September 1808 19 July 1809 Joseph I 58 Francisco Javier de Lizana y Beaumont (Archbishop of Mexico )19 July 1809 8 May 1810 Ferdinand VII 59 Pedro Catani 8 May 1810 14 September 1810 60 Francisco Javier Venegas , 1st Marquess of Reunión and of New Spain14 September 1810 4 March 1813 61 Félix María Calleja del Rey , 1st Count of Calderón4 March 1813 20 September 1816 62 Juan Ruiz de Apodaca , 1st Count of Venadito20 September 1816 5 July 1821 63 Francisco Novella Azabal Pérez y Sicardo 15 July 1821 21 July 1821 64 Juan O'Donojú 21 July 1821 28 September 1821